Unfolding Mystery

Why Does Hot Water Sometimes Freeze Faster Than Cold?

The Mpemba effect — a paradox that stumped Aristotle and still lacks a single accepted explanation.

[curious] Have you ever put both hot and cold water in the freezer and found, to your surprise, that the hot water froze first? This seemingly impossible phenomenon challenges our basic understanding of how heat and cold work. How could something that starts out hotter possibly reach freezing point before something already cold? The answer seems obvious. Cold water must freeze faster because it's already closer to freezing temperature. Hot water needs to cool down first, then freeze. Basic thermodynamics tells us that cooling happens at a rate proportional to the temperature difference. So hot water has farther to go, and should take longer. Yet for centuries, people have observed the opposite. Hot water sometimes freezes faster than cold water, even when starting from the same container in the same freezer. This direct contradiction to what physics seemingly tells us should happen is what makes this mystery so compelling. This phenomenon has a name: the Mpemba effect, named after Erasto Mpemba, a Tanzanian student who noticed it while making ice cream in the nineteen-sixties.

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